Jpn. J. Appl. Phys. 13 (1974) pp. 773-778  |Next Article|  |Table of Contents|
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Growth of Bilayered NiO Scales on Nickel

Tokihiro Ueno

(Received October 29, 1973)

Four types of bilayered scale of NiO are formed on nickel in air over the temperature range of 900 to 1200°C. Growth rates of the bilayer are determined by measuring its thickness. Growth rates of different types of bilayer are compared with each other. According to the colour and the electrical resistivity, the green zone in bilayer is closely stoichiometric, while the black zone in bilayer has an excess of oxygen. Growth mechanisms of bilayer are discussed.

URL: http://jjap.jsap.jp/link?JJAP/13/773/
DOI: 10.1143/JJAP.13.773

References | Citing Articles (4)

1. A. Preece and G. Lucus: J. Inst. Metals 81 (1952) 219.
2. B. Ilschner and H. Pfeiffer: Naturwissenschaften 23 (1953) 603.
3. J. A. Sartel and C. H. Li: J. Inst. Metals 90 (1961) 92.
4. B. M. Vasyutinsky and G. N. Kartomazov: Fiz. Metallov Metallovedenie 15 (1963) 132.
5. G. C. Wood and I. G. Wright: Corrosion Sci. 5 (1965) 841.
6. V. I. Arkharov, S. I. Ivanovskaya and A. S. Krinovosova: Fiz. Metallov Metallovedenie 22 (1966) 884.
7. N. Terao: Jpn. J. Appl. Phys. 10 (1971) 1256[JSAP].
8. T. Ueno: Trans. Japan Inst. Metals 14 (1973) 267.
9. A. G. Evans, Dilip Rajdev and D. L. Douglass: Oxid. Metals 4 (1972) 151.
10. E. A. Gulbransen and K. F. Andrews: J. Electrochem. Soc. 105 (1958) 363.
11. A. Dravnicks and H. J. McDonald: J. Electrochem. Soc. 94 (1948) 139.
12. T. Homma: Rep. Inst. Industr. Sci. Univ. Tokyo 15 (1965) 165.
13. D. L. Douglass: Oxid. Metals 1 (1969) 124.
14. F. N. Rhines and J. S. Wolf: Metall. Trans. 1 (1970) 1701.
15. Cf. for example, P. Kofstad: High-Temperature Oxidation of Metals (John Wily & Sons, New York, 1966) p. 11.
16. Cf. for example, F. J. Morin: Semiconductor ek. N. B. Hanney (Reinhold, New York, 1959) p. 610.
17. R. Newman and R. M. Chrenko: Phys. Rev. 114 (1959) 1507[APS].
18. E. J. W. Verwey: Chem. Weekblad 44 (1948) 705.
19. R. W. Right and J. P. Andrews: Proc. Phys. Soc. A62 (1949) 446.
20. F. J. Morin: Phys. Rev. 93 (1954) 1199[APS].
21. D. P. Snowden and H. Saltsburg: Phys. Rev. Lett. 14 (1965) 497[APS].
22. N. Birks and H. Rickert: J. Inst. Metals 91 (1963) 308.
23. Cf. for example, O. Kubaschewski and N. B. Hopkins: Oxidation of Metals and Alloys (Butterwoths, London, 1962) p. 168.
24. R. Herchl and N. N. Khoi, T. Homma and W. W. Smeltzer: Oxid. Metals 4 (1972) 35.
25. H. R. Thornton: Ph. D. Thesis, University of Illinois (1963).
26. C. M. Osburn and R. W. Vest: J. Phys. Chem. Solids 32 (1971) 1355.
27. K. T. Aust and B. Chalmers: Metall. Trans. 1 (1970) 1095.
28. Cf. for example, P. Kofstad: High-Temperature Oxidation of Metals (John Wily & Sons, 1966) p. 140.
29. M. T. Shim and W. J. Moore: J. Chem. Phys. 26 (1957) 802[AIP Scitation].
30. M. L. Volpe and J. Reddy: J. Chem. Phys. 53 (1370) 1117[AIP Scitation].
31. M. O'Keeffe and W. J. Moore: J. Phys. Chem. 65 (1961) 1438.
32. C. Wagner: Atom Movements (Amer. Soc. Metals, Cleaveland, 1951) p. 153.
33. R. E. Carter and F. D. Richardson: Trans. AIME 200 (1954) 1244.
34. J. S. Choi and W. J. Moore: J. Chem. Phys. 66.
35. W. J. Moore, Y. Ebisuzaki and J. A. Sluss: J. Phys. Chem. 62 (1958) 1438.
36. R. E. Pawel and J. J. Campbell: Acta Metall. 14 (1966) 1827.
37. T. Ueno: to be published in Trans. Japan Inst. Metals 15 (1974) No. 3.