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Photoluminescence Study of Defects in GaAs Formed by Annealing in an H2 Gas Flow

Mutsuyuki Otsubo, Hidejiro Miki and Shigeru Mitsui

Central Research Laboratories, Mitsubishi Electric Corporation

(Received April 11, 1977)

GaAs crystals were annealed in an H2 gas flow and the degraded layer formed on the surface by annealing has been investigated by a photoluminescence measurement. The origin of the defects, in particular an emission at 890 nm, formed by annealing has also been investigated with the aid of the liquid phase epitaxy technique. The degradation of the surface is governed by self-diffusion of As vacancies. The degraded layer depth increases in proportion to the square root of the heating time, whose rate depends on carrier concentrations in the crystals. As the crystals are annealed in an H2 gas flow, new emission band at 890 nm grows drastically. It is concluded that the band is due to electron transitions from a shallow donor to an As vacancy acceptor.

URL: http://jjap.jsap.jp/link?JJAP/16/1957/
DOI: 10.1143/JJAP.16.1957


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References | Citing Articles (13)

  1. C. S. Fuller and K. B. Wolfstrin: J. Appl. Phys. 34 (1963) 2287[AIP Scitation].
  2. S. P. Grishina, M. G. Milvidskii, V. B. Osvenskii and V. I. Fistul: Soviet Phys.-Semiconductors 4 (1970) 240.
  3. I. V. Mitchell, J. W. Mayer, J. K. Kung and W. G. Spitzer: J. Appl. Phys. 42 (1971) 3982[AIP Scitation].
  4. J. T. Edmond: J. Appl. Phys. 31 (1960) 1428[AIP Scitation].
  5. J. Blanc, R. H. Bube and L. R. Weisberg: J. Phys. Chem. Solid 25 (1964) 225.
  6. H. R. Potts and G. L. Pearson: J. Appl. Phys. 37 (1966) 2098[AIP Scitation].
  7. C. S. Fuller, K. B. Wolfstrin and H. W. Allison: J. Appl. Phys. 38 (1967) 4339[AIP Scitation].
  8. H. Otsuka, K. Ishida and J. Nishizawa: Jpn. J. Appl. Phys. 8 (1969) 632[JSAP].
  9. C. J. Hwang: J. Appl. Phys. 40 (1969) 1983[AIP Scitation].
  10. M. Toyama: Jpn. J. Appl. Phys. 8 (1969) 1000[JSAP].
  11. J. S. Harris, Y. Nannichi and G. L. Pearson: J. Appl. Phys. 40 (1969) 4575[AIP Scitation].
  12. E. Mūnoz, W. L. Snyder and J. L. Moll: Appl. Phys. Lett. 16 (1970) 262[AIP Scitation].
  13. T. Ito and M. Takeuchi: Jpn. J. Appl. Phys. 16 (1977) 227[JSAP].
  14. K. Okada and T. Oku: Jpn. J. Appl. Phys. 6 (1967) 276[JSAP].
  15. D. E. Hill: Phys. Rev. 133 (1964) A866[APS].
  16. H. Kressel, F. Z. Hawrylo and P. LeFur: J. Appl. Phys. 39 (1968) 4059[AIP Scitation].
  17. E. W. Williams: Phys. Rev. 168 (1968) 922[APS].
  18. E. W. Williams and H. B. Bebb: Semiconductors and Semimetals, eds. R. K. Willardson and A. C. Beer (Academic Press, New York, 1972) Vol. 8, Chap. 5, p. 321.
  19. C. J. Hwang: J. Appl. Phys. 38 (1967) 4811[AIP Scitation].
  20. C. J. Hwang: J. Appl. Phys. 38 (1967) 4307[AIP Scitation].
  21. M. Jeong, J. Shirafuji and Y. Inuishi: Jpn. J. Appl. Phys. 12 (1973) 109[JSAP].
  22. H. Kressel, J. U. Dunse, H. Nelson and F. Z. Hawrylo: J. Appl. Phys. 39 (1968) 2006[AIP Scitation].
  23. H. Kressel, F. Z. Hawrylo, M. S. Abraham and C. J. Buuoichi: J. Appl. Phys. 39 (1968) 5139[AIP Scitation].
  24. M. Otsubo and H. Miki: Jpn. J. Appl. Phys. 14 (1975) 621[JSAP].
  25. D. L. Kendall: Semiconductors and Semimetals, eds. R. K. Willardson and A. C. Beer (Academic Press, New York, 1968) Vol. 4, p. 163.
  26. H. J. Queiser: J. Appl. Phys. 37 (1966) 2909[AIP Scitation].
  27. E. W. Williums and C. T. Elliot: Brit. J. Appl. Phys. (J. Phys. D) 2 (1969) 1657.
  28. L. L. Chang, L. Esaki and R. tsu: Appl. Phys. Lett. 19 (1971) 143[AIP Scitation].
  29. R. Romano-Moran and K. L. Ashley: J. Phys. Chem. Solids 34 (1973) 427.
  30. W. G. Spitzer and W. Allred: Appl. Phys. Lett. 12 (1968) 5[AIP Scitation].
  31. SARGENT-WELCH SCIENTIFIC COMPANY, Catalog No. S-18806, 1968.
  32. F. E. Rosztoczy, F. Ermanis, I. Hayashi and B. Schwartz: J. Appl. Phys. 41 (1970) 264[AIP Scitation].
  33. H. Stack: Trans. Metall. Soc. AIME 239 (1967) 381.
  34. R. H. Haisty: Appl. Phys. Lett. 7 (1965) 208[AIP Scitation].
  35. M. Ilegems, R. Dingle and L. W. Rupp Jr.: J. Appl. Phys. 46 (1975) 3059[AIP Scitation].
  36. S. Y. Chiang and G. L. Pearson: J. Appl. Phys. 46 (1975) 2986[AIP Scitation].

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