Jpn. J. Appl. Phys. 26 (1987) pp. L1546-L1549 |Next Article| |Table of Contents|
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Letter
Superconductivity of La1+xBa2-xCu3Oy System: Which Layers are Doped with Carriers?
Eiji Takayama-Muromachi,
Yoshishige Uchida,
Atsushi Fujimori and
Katsuo Kato
National Institute for Research in Inorganic Materials
(Received July 30, 1987; accepted for publication August 17, 1987)
The La1+xBa2-xCu3Oy system was examined by means of ac susceptibility measurement and thermogravimetry. The superconducting transition point is affected by the La/Ba ratio: Tc decreases monotonously with increasing x, and the sample having x of at least 0.3 did not show superconductivity above 4.2 K. Moreover, it was found that Tc was dramatically reduced by the introduction of a very small quantity of oxygen defects into the rock-salt-type Ba-O layers (2g site in P4/mmm). From this fact and earlier results on YBa2Cu3Oy and La2-xSrxCuO4, we suggest that charge carriers are holes doped mainly in the O 2p orbitals of the Ba-O layers, being consistent with a large number of experimental results reported thus far.
URL:
http://jjap.jsap.jp/link?JJAP/26/L1546/
DOI: 10.1143/JJAP.26.L1546
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