Jpn. J. Appl. Phys. 27 (1988) pp. 2192-2198  |Next Article|  |Table of Contents|
|Full Text PDF (1105K)| |Buy This Article|

Effects of Ions on Properties of a-Si:H Films Prepared by ECR Plasma CVD Method

Koji Akiyama, Eiichiro Tanaka, Akio Takimoto and Masanori Watanabe

Central Research Laboratories, Matsushita Electric Industrial Co., Ltd.

(Received January 11, 1988; revised manuscript revised August 10, 1988; accepted for publication October 22, 1988)

A study has been made on the effect of ions on the structural and electrical properties of a-Si:H films prepared by ECR plasma CVD method using H2, He and Ar as a plasma generation gas and SiH4. Deposition rates of over 10 µm/h can be achieved with H2 and He plasma, while Ar plasma generation attains half the deposition rates of H2 and He plasma. The increase of (SiH2)n chains in films is related to the reduced microwave power, increased pressure and positive DC bias voltage being applied to the substrates. The concentration of (SiH2)n chains dominates the photoconductivities. Films having the low concentration of (SiH2)n have ηµτ of 6×10-7 cm2/V after the depositions without substrate heating and 6×10-6 cm2/V after annealing at 280degC for 30 min. The energy transfer of incident ions to the film surface plays the most important role in obtaining highly photoconductive films.

URL: http://jjap.jsap.jp/link?JJAP/27/2192/
DOI: 10.1143/JJAP.27.2192


|Full Text PDF (1105K)| |Buy This Article| Citation:


References | Citing Articles (15)

  1. D. E. Carlson and C. R. Wronski: Appl. Phys. Lett. 28 (1976) 671[AIP Scitation].
  2. N. Yamamoto, Y. Nakayama, K. Wakita, M. Nakano and T. Kawamura: Proc. 12th Conf. on Solid State Devices, Tokyo, 1980, Jpn. J. Appl. Phys. 20 (1981) Suppl. 20-1, p. 305[JSAP].
  3. T. Kagawa, N. Matsumoto and K. Kumabe: Proc. of 13th Conf. Solid State Devices, Tokyo, 1981, Jpn. J. Appl. Phys. 21 (1982) Suppl. 21-1, p. 251[JSAP].
  4. A. J. Snell, K. D. Mackenzie, W. E. Spear and P. G. LeComber: Appl. Phys. 24 (1981) 375.
  5. J. C. Knights: Proc. 10th Conf on Solid State Devices, Tokyo, 1978, Jpn. J. Appl. Phys. 18 (1978) Suppl. 18-1, p. 101[JSAP].
  6. K. Tanaka, K. Nakagawa, A. Matsuda, M. Matsumura, H. Yamamoto, S. Yamasaki, H. Okushi and S. Iijima: 12th Conf on Solid State Devices, Tokyo, 1980, Jpn. J. Appl. Phys. 20 (1981) Suppl. 20-1, p. 267[JSAP].
  7. H. Shimada, S. Mizuno and M. Noda: Jpn. J. Appl. Phys. 25 (1986) 775[JSAP].
  8. I. Kato, H. Tsuchida and M. Nagai: J. Appl. Phys. 51 (1980) 5312[AIP Scitation].
  9. S. Matsuo and M. Kikuchi: Jpn. J. Appl. Phys. 22 (1983) L210[JSAP].
  10. Y. Manabe, T. Mitsuyu and O. Yamasaki: Extended Abstracts of 18th Conf. on Solid State Devices and Material, Tokyo, 1986 (Business Center for Academic Societies, Tokyo, 1986) p. 241.
  11. M. Kitagawa, K. Setsune, Y. Manabe and T. Hirao: J. Appl. Phys. 61 (1987) 2084[AIP Scitation].
  12. M. Kitagawa, S. Ishihara, K. Setsune, Y. Manabe and T. Hirao: Jpn. J. Appl. Phys. 26 (1987) L231[JSAP].
  13. M. Kitagawa, S. Ishihara, Y. Manabe, K. Setsune and T. Hirao: Proc. 8th Int. Symp. on Plasma Chemistry, Tokyo, 1987, (Int. Union of Pure & Appl. Chemistry, Tokyo, 1987) p. 1442.
  14. K. Kobayashi, M. Hayama, S. Kawamoto and H. Miki: Jpn. J. Appl. Phys. 26 (1987) 202[JSAP].
  15. T. Watanabe, K. Azuma, M. Nakatani, K. Suzuki, T. Sonobe and T. Shimada: Jpn. J. Appl. Phys. 25 (1986) 1805[JSAP].
  16. T. Watanabe, M. Tanaka, K. Azuma, M. Nakatani, T. Sonobe and T. Shimada: Jpn. J. Appl. Phys. 26 (1987) 1215[JSAP].
  17. Y. Nakayama, T. Natsuhara, N. Nagasawa and T. Kawamura: Jpn. J. Appl. Phys. 21 (1982) L604[JSAP].
  18. N. Laegreid and G. K. Wehner: J. Appl. Phys. 32 (1961) 365[AIP Scitation].
  19. P. J. Zanzucchi, C. R. Wronski and D. E. Carlson: J. Appl. Phys. 48 (1977) 5227[AIP Scitation].
  20. H. Okamoto, Y. Nitta, T. Yamaguchi and Y. Hamakawa: Sol. Energy Mater. 2 (1980) 313.
  21. K. Suzuki, S. Nishimatsu, K. Ninomiya and S. Okudaira: Technical Papers of Electrical Discharge Committee IEE, Jpn. ED-82-11 (1982) 11.
  22. M. Miyamura, O. Tsukakoshi and S. Komiya: Technical Papers of Electrical Discharge Committee IEE, Jpn. ED-82-10 (1982) 1.
  23. T. Ono, M. Oda, C. Takahashi and S. Matsuo: J. Vac. Sci. & Technol. B4 (1986) 696.
  24. J. C. Knights: J. Non-Cryst. Solids., 35/36 (1980) 159.
  25. R. A. Street: Philos. Mag. B46 (1982) 273.
  26. T. Shimizu, K. Nakazawa, M. Kumeda and S. Ueda: Physica 117/118 (1983) 926.
  27. J. J. Loferski and P. Rappaport: Phys. Rev. 100 (1955) 1261, [APS] and Phys. Rev. 111 (1958) 432[APS].
  28. D. K. Biegelsen, R. A. Street, C. C. Tsai and J. C. Knights: Phys. Rev. B20 (1979) 4839[APS].

|TOP|  |Next Article|  |Table of Contents| |JJAP Home|
Copyright © 2013 The Japan Society of Applied Physics
Contact Information