Jpn. J. Appl. Phys. 43 (2004) pp. 186-187 |Previous Article| |Next Article| |Table of Contents|
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Short Note
Tailoring of Luminous Transmittance upon Switching for Thermochromic VO2 Films by Thickness Control
Gang Xu,
Ping Jin,
Masato Tazawa and
Kazuki Yoshimura
National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Shidami, Moriyama-ku, Nagoya 463-8560, Japan
(Received July 28, 2003; accepted October 14, 2003; published January 13, 2004)
The difference in luminous transmittance (ΔTlum) upon switching of VO2 films strongly affects its solar controllability when used as a thermochromic window. It was found that ΔTlum is controllable by film thickness. Optical calculation for a VO2 film on quartz glass revealed that the low-temperature semiconductor phase exhibits lower Tlum than the high-temperature metallic phase for thickness below 50 nm, while the relationship is reversed above 50 nm. The calculation was confirmed by film deposition and measurement. Maximum ΔTlum is located near 80 nm. An enhanced ΔTlum contributes largely to solar efficiency.
URL:
http://jjap.jsap.jp/link?JJAP/43/186/
DOI: 10.1143/JJAP.43.186
KEYWORDS:vanadium dioxide, thin film, refractive index, luminous transmittance, optical design, energy-efficient window
- C. G. Granqvist: Materials Science for Solar Energy Conversion Systems (Pergamon Press, Oxford, 1991) Chap. 5.
- S. M. Babulanam, T. S. Eriksson, G. A. Niklasson and C. G. Granqvist: Sol. Energy Mater. 16 (1987) 347.
- F. J. Morin:
Phys. Rev. Lett. 3 (1959) 34[APS].
- J. B. Goodenough:
J. Solid State Chem. 3 (1971) 490[CrossRef].
- B. L. Chamberland: Mater. Res. Bull. 6 (1971) 425.
- P. Jin and S. Tanemura:
Jpn. J. Appl. Phys. 34 (1995) 2459[JSAP].
- O. S. Heavens: Optical Properties of Thin Solid Films (Dover Publication, New York, 1991) Chap. 4.
- Annual Book of ASTM Standards (American Society for Testing & Materials, Easton, 1987) Vol. 12.02, p. 176, 832.
- J. T. Swann and D. J. De Smet:
J. Appl. Phys. 58 (1985) 1335[AIP Scitation].
- M. Tazawa, P. Jin and S. Tanemura: Appl. Opt. 37 (1998) 1858.