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Dynamic Nuclear Polarization of 29Si Nuclei Induced by Li and Li–O Centers in Silicon
Mohammad R. Rahman,
Tatsumasa Itahashi,
Marina P. Vlasenko1,
Leonid S. Vlasenko1,
Eugene E. Haller2, and
Kohei M. Itoh
School of Fundamental Science and Technology, Keio University, Yokohama 223-8522, Japan
1A. F. Ioffe Physico-Technical Institute, 194021 St. Petersburg, Russia
2Lawrence Berkeley National Laboratory and UC Berkeley, 1 Cyclotron Rd., Berkeley, CA 94720, U.S.A.
(Received June 4, 2010; accepted July 23, 2010; published online October 20, 2010)
Dynamic nuclear polarization (DNP) of 29Si nuclear spins induced by saturation of electron paramagnetic resonance (EPR) transitions of lithium-related centers in float zone (FZ) grown silicon is reported. Both isolated Li and Li–O complex centers showed strong EPR absorption lines in the temperature range 3.4–10 K and led to very efficient orientation of 29Si nuclear spins. The temperature dependence and time constant of 29Si DNP are investigated in detail. The 29Si DNP of 0.72% was achieved at 3.4 K by excitation of the Li–O forbidden EPR transition under illumination, corresponding to a ∼352 fold increase with respect to the thermal equilibrium polarization.
URL:
http://jjap.jsap.jp/link?JJAP/49/103001/
DOI: 10.1143/JJAP.49.103001
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