Jpn. J. Appl. Phys. 51 (2012) 04DP07 (4 pages)  |Previous Article| |Next Article|  |Table of Contents|
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Optimization of Amorphous Si/Crystalline Si Heterojunction Solar Cells by BF2 Ion Implantation

Tzong-Han Tsai, Yung-Chun Wu, Shih-Sian Yang, and Chun-Hao Chen

Department of Engineering and System Science, National Tsing Hua University, Hsinchu 300, Taiwan

(Received September 26, 2011; accepted December 12, 2011; published online April 20, 2012)

In this study we evaluated two approaches to improving the efficiency of amorphous Si/crystalline Si (a-Si/c-Si) heterojunction solar cells by BF2 ion implantation. First, emitter layer formation was compared for the cases of B and BF2 ion implantation when using the same 7° tilt angle. Second, emitter layer formation was compared between a 7° tilt angle and a 60° tilt angle when using BF2 ion implantation. The experimental results reveal that the fluorine in BF2 passivates the defects at the a-Si and a-Si/c-Si interface, and ion implantation at a high 60° tilt angle forms a shallow solar cell junction. The emitter layer formed by BF2 ion implantation with a 60° tilt angle in an a-Si/c-Si heterojunction solar cell achieves the highest short circuit current density (JSC) of 36.85 mA/cm2 with a conversion efficiency (η) of 14.41%.

URL: http://jjap.jsap.jp/link?JJAP/51/04DP07/
DOI: 10.1143/JJAP.51.04DP07


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References

  1. M. Schmidt, L. Korte, A. Laades, R. Stangl, and Ch. Schubert: Thin Solid Films 515 (2007) 7475[CrossRef].
  2. T. Sawada, N. Terada, S. Tsuge, T. Baba, T. Takahama, K. Wakisaka, S. Tsuda, and S. Nakano: IEEE Photovoltaic Specialists Conf., 1994, p. 1219.
  3. M. A. Green: Solar Cells: Operating Principles, Technology and System Applications (Prentice Hall, Englewood Cliffs, NJ, 1982) p. 144.
  4. J. D. Plummer, M. D. Deal, and P. B. Griffin: Silicon VLSI Technology: Fundamentals, Practice and Modeling (Prentice Hall, Upper Saddle River, NJ, 2000).
  5. M. Taguchi, H. Sakata, Y. Yoshimine, E. Maruyama, A. Terakawa, and M. Tanaka: Photovoltaic Specialists Conf., 2005, p. 866.
  6. M. B. Spitzer, S. P. Tobin, and C. J. Keavney: IEEE Trans. Electron Devices 31 (1984) 546[CrossRef].
  7. M. A. Green: IEEE Trans. Electron Devices 31 (1984) 679[CrossRef].
  8. H. Fujiwara, T. Kaneko, and M. Kondo: Appl. Phys. Lett. 91 (2007) 133508[AIP Scitation].
  9. Z. Chen, S. K. Pang, K. Yasutake, and A. Rohatgi: J. Appl. Phys. 74 (1993) 2856[AIP Scitation].
  10. A. Limmanee, M. Ohtsubo, T. Sato, S. Miyajima, A. Yamada, and M. Konagai: Proc. 4th World Conf. Photovoltaic Energy Conversion, 2006, p. 1227.
  11. M. Taguchi, K. Kawamoto, S. Tsuge, T. Baba, H. Sakata, M. Morizane, K. Uchihashi, N. Nakamura, S. Kiyama, and O. Oota: Prog. Photovoltaics 8 (2000) 503.
  12. J. Zhao, A. Wang, and M. A. Green: Sol. Energy Mater. Sol. Cells 65 (2001) 429.
  13. A. Madan, S. R. Ovshinsky, W. Czubatyj, and M. Shur: J. Electron. Mater. 9 (1984) 385.
  14. SRIM (ver. 2008.04) [http://www.srim.org].
  15. C. H. Tu, T. C. Chang, P. T. Liu, C. Y. Yang, H. C. Liu, W. R. Chen, Y. C. Wu, and C. Y. Chang: IEEE Electron Device Lett. 27 (2006) 262[CrossRef].

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