Jpn. J. Appl. Phys. 51 (2012) 04DP07 (4 pages) |Previous Article| |Next Article| |Table of Contents|
|Full Text PDF (583K)| |Buy This Article|
Optimization of Amorphous Si/Crystalline Si Heterojunction Solar Cells by BF2 Ion Implantation
Tzong-Han Tsai,
Yung-Chun Wu,
Shih-Sian Yang, and
Chun-Hao Chen
Department of Engineering and System Science, National Tsing Hua University, Hsinchu 300, Taiwan
(Received September 26, 2011; accepted December 12, 2011; published online April 20, 2012)
In this study we evaluated two approaches to improving the efficiency of amorphous Si/crystalline Si (a-Si/c-Si) heterojunction solar cells by BF2 ion implantation. First, emitter layer formation was compared for the cases of B and BF2 ion implantation when using the same 7° tilt angle. Second, emitter layer formation was compared between a 7° tilt angle and a 60° tilt angle when using BF2 ion implantation. The experimental results reveal that the fluorine in BF2 passivates the defects at the a-Si and a-Si/c-Si interface, and ion implantation at a high 60° tilt angle forms a shallow solar cell junction. The emitter layer formed by BF2 ion implantation with a 60° tilt angle in an a-Si/c-Si heterojunction solar cell achieves the highest short circuit current density (JSC) of 36.85 mA/cm2 with a conversion efficiency (η) of 14.41%.
URL:
http://jjap.jsap.jp/link?JJAP/51/04DP07/
DOI: 10.1143/JJAP.51.04DP07
References
- M. Schmidt, L. Korte, A. Laades, R. Stangl, and Ch. Schubert:
Thin Solid Films 515 (2007) 7475[CrossRef].
- T. Sawada, N. Terada, S. Tsuge, T. Baba, T. Takahama, K. Wakisaka, S. Tsuda, and S. Nakano: IEEE Photovoltaic Specialists Conf., 1994, p. 1219.
- M. A. Green: Solar Cells: Operating Principles, Technology and System Applications (Prentice Hall, Englewood Cliffs, NJ, 1982) p. 144.
- J. D. Plummer, M. D. Deal, and P. B. Griffin: Silicon VLSI Technology: Fundamentals, Practice and Modeling (Prentice Hall, Upper Saddle River, NJ, 2000).
- M. Taguchi, H. Sakata, Y. Yoshimine, E. Maruyama, A. Terakawa, and M. Tanaka: Photovoltaic Specialists Conf., 2005, p. 866.
- M. B. Spitzer, S. P. Tobin, and C. J. Keavney:
IEEE Trans. Electron Devices 31 (1984) 546[CrossRef].
- M. A. Green:
IEEE Trans. Electron Devices 31 (1984) 679[CrossRef].
- H. Fujiwara, T. Kaneko, and M. Kondo:
Appl. Phys. Lett. 91 (2007) 133508[AIP Scitation].
- Z. Chen, S. K. Pang, K. Yasutake, and A. Rohatgi:
J. Appl. Phys. 74 (1993) 2856[AIP Scitation].
- A. Limmanee, M. Ohtsubo, T. Sato, S. Miyajima, A. Yamada, and M. Konagai: Proc. 4th World Conf. Photovoltaic Energy Conversion, 2006, p. 1227.
- M. Taguchi, K. Kawamoto, S. Tsuge, T. Baba, H. Sakata, M. Morizane, K. Uchihashi, N. Nakamura, S. Kiyama, and O. Oota: Prog. Photovoltaics 8 (2000) 503.
- J. Zhao, A. Wang, and M. A. Green: Sol. Energy Mater. Sol. Cells 65 (2001) 429.
- A. Madan, S. R. Ovshinsky, W. Czubatyj, and M. Shur: J. Electron. Mater. 9 (1984) 385.
- SRIM (ver. 2008.04) [http://www.srim.org].
- C. H. Tu, T. C. Chang, P. T. Liu, C. Y. Yang, H. C. Liu, W. R. Chen, Y. C. Wu, and C. Y. Chang:
IEEE Electron Device Lett. 27 (2006) 262[CrossRef].